[(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
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چکیده
منابع مشابه
Tetrakis(triphenylarsane-κAs)silver(I) trifluoroacetate hemihydrate methanol hemisolvate
The Ag(I) atom in the title hydrated solvated salt, [Ag(C18H15As)4](CF3CO2)·0.5CH3OH·0.5H2O, is coordinated by four As atoms from triphenyl-arsane ligands in a distorted tetra-hedral geometry. In the crystal, O-H⋯O hydrogen bonding occurs between carboxyl-ate groups of anions and lattice solvent mol-ecules. Of the four triphenyl-arsane ligands in the Ag complex cation, two each have an equally ...
متن کامل[(–)-(1S,2S)-N,N′-Bis(2-oxidobenzylidene)-1,2-diphenylethane-1,2-diamine]bis(pyridine)cobalt(III) perchlorate methanol hemisolvate hemihydrate
In the title compound, [Co(C(28)H(22)N(2)O(2))(C(5)H(5)N)(2)]ClO(4)·0.5CH(4)O·0.5H(2)O, each Co(III) ion is coordinated by the tetra-dentate N,N'-bis-(2-oxidobenzyl-idene)-1,2-diphenyl-ethane-1,2-diamine ligand [Co-N = 1.900 (3) and 1.903 (3) Å; Co-O = 1.885 (3) and 1.891 (3) Å] and two pyridine ligands [Co-N = 1.967 (4) and 1.977 (3) Å] in a distorted octa-hedral geometry. The packing of the c...
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The title compound, C22H24N2O7S·0.5C2H5OH·0.5H2O {systematic name: (S)-4-acetamido-2-[1-(3-eth-oxy-4-meth-oxy-phen-yl)-2-(methyl-sulfon-yl)eth-yl]iso-indo-line-1,3-dione ethanol hemisolvate hemihydrate}, is a novel solvatomorph of apremilast (AP), which is an inhibitor of phosphodiesterase 4 (PDE4) and is indicated for the treatment of adult patients with active psoriatic arthritis. The asymmet...
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The asymmetric unit of the title compound, C24H16N2·0.5CH3OH, is comprised of two independent bathophenanthroline mol-ecules (systematic name: 4,7-diphenyl-1,10-phenanthroline) and one methanol mol-ecule. The bathophenanthroline mol-ecules are not planar as there is a considerable rotation of all terminal phenyl rings with respect to the central phenanthroline units [dihedral angles in the rang...
متن کاملBis(2,2′:6′,2′′-terpyridine)ruthenium(II) bis(perchlorate) hemihydrate
The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium-terpiridine complex cation, two perchlorate anions and one half-mol-ecule of water. Face-to-face and face-to-edge π-stacking inter-actions between terpyridine units [centroid-centroid distances = 3.793 (2) and 3.801 (2) Å] stabilize the crystal lattice The partially occupied water mol...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808031887